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Ours came with this little brick thing that I think is supposed to keep mineral buildup from accumulating, but the company stopped making that humidifier and we can't buy any more of the bricks. We'll probably be shopping for another one next season. :(
The brick was probably just citric acid. Buy a bag from your local supermarket, you'll find it in the kitchen section probably as a crystalline powder, and dump some of that in the humidifier water to also prevent buildup.
Fun fact, you can also run a larger amount of it through your empty dishwasher instead of those dishwasher cleaner packs; those are mostly citric acid too. Cheaper, and no horrible fake lavender scent or whatever it is they like to put in the packs.
Edit: the bricks could also have been hypochlorous acid which is available from various vendors: