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Endogenous vitamins.
I'm not sure I understand.
What would this do and how would it work?
There are things like vitamin C and D your body has to get from somewhere else. Food, sunlight. Other animals don't have this issue. Every creature is built different, i just wish we were a little lower maintenance - or failing that, a good answer why it has to be this way.
Infodump incoming:
Amino acids are the basic building blocks of life. DNA encodes which animo acids to put together in which order, and when. Ribosomes read bits of RNA that was copied from DNA and match up amino acids. The different animo acids correspond to different three nucleotides combinations (the As, Cs, Gs, and Ts of DNA). The ribosome attaches each animo acid in a chain.
When the amino acid chain detaches from the ribosome it folds into a protein. Different amino acids in different orders affect how the protein folds and what it becomes. Proteins are the structures and machinery of our cells.
There are 20 amino acids we need to make the proteins we rely on. Our bodies can make some of them and some of them we can't. The ones our bodies can't make we have to get from our diet. Those ones are called vital amines, or vitamins for short.