No idea, if there's a GUI to schedule it, but you seem to be running Arch, so presumably you won't have a problem with scripting.
This command works for me on Plasma 5 to set the brightness:
qdbus-qt5 org.kde.Solid.PowerManagement /org/kde/Solid/PowerManagement/Actions/BrightnessControl org.kde.Solid.PowerManagement.Actions.BrightnessControl.setBrightness 123
Presumably, you need qdbus-qt6
or just qdbus
, I don't know.
Well, and then just stick that in two cron jobs with different values in place of 123
.